Synthesis and enhanced photocatalytic performance of Ni2+-doped Bi4O7 nanorods with broad-spectrum photoresponse

• Developing a facile hydrothermal strategy for assembling Ni 2+ -doped Bi 4 O 7 nanorods. • The doping narrows band gap and contributes to separating photoproduced carriers. • The composites are broad-spectrum photoresponsive in degrading organic pollutants. To fully utilize the solar energy, developing a suitable photocatalyst with broad-spectrum photoresponse is crucial in the degradation of water contaminants. In this work, Ni 2+ -doped Bi 4 O 7 nanorods are prepared through a facile hydrothermal procedure. Various characterization techniques are adopted to explore the structure‐photocatalytic performance relationships of the obtained materials in degrading organic dye rhodamine B (RhB) and antibiotic ciprofloxacin (CIP). Compared with that of the pristine Bi 4 O 7 , the Ni 2+ -doping enlarges the specific surface area, lowers the band gap energy and reduces the electrons-holes recombination, thus improving photocatalytic performance. Catalyzed by the optimal 4 % Ni/Bi 4 O 7 (20.0 mg), the elimination efficiencies of RhB and CIP (10.0 mg/L, 50.0 mL) are 97 % and 96 % within 2 h irradiated by visible light, respectively, which are obviously higher than that of Bi 4 O 7 . Also, the doped semiconductor exhibits satisfactory cycling stability. In addition, the possible photocatalytic degradation procedures of the pollutants and the plausible photocatalytic mechanism of the resulting composites are proposed. The excellent photocatalytic performance, low cost and facile preparation strategy endow the as-prepared 4 % Ni/Bi 4 O 7 with broad-spectrum photoresponse a promising potential in environmental remediation.