Constructing 3D Crosslinked Macromolecular Networks as a Highly Efficient Interface Layer for Ultra‐Stable Zn Metal Anodes

Aqueous zinc ion batteries (AZIBs) are experiencing rapid development due to their high theoretical capacity, abundant zinc resources, and intrinsic safety. However, the progress of AZIBs is hindered by uncontrollable parasitic reactions and excessive dendrite growth, which compromise the durability and effective utilization of zinc metal anodes. To address these challenges, the study has constructed a 3D crosslinked macromolecular network composed of zinc ion-bonded potato starch (StZ) as an interface layer on Zn foil (StZ-Zn) to inhibit hydrogen evolution, regulate Zn