过电位
材料科学
电化学
电解质
循环伏安法
阳极
析氧
化学工程
冶金
电极
化学
物理化学
工程类
作者
Yuda Prima Hardianto,Md. Abdul Aziz,Md. Abdul Aziz,Zain H. Yamani
标识
DOI:10.1002/asia.202400118
摘要
Abstract The study examines the oxygen evolution reaction (OER) electrocatalytic efficiency of various stainless‐steel mesh (SSM) sizes in electrolytic cells. Stainless steel is chosen due to its widespread availability and stability, making it an economically viable option. The primary objective of this investigation is to determine the optimal stainless‐steel mesh size among those currently widely available on the market. The classification of stainless‐steel mesh sizes as SS304 is confirmed by the minimal compositional variations observed across all mesh sizes through electron dispersive X‐ray (EDX) spectra and X‐ray fluorescence (XRF) analyses. Remarkably, CV experiments carried out at different scan rates indicate that SSM 200 has the maximum specific electrochemical surface area (ECSA). As a result, SSM 200 demonstrates superior performance in terms of current density response and shows the lowest overpotential in the alkaline medium compared to other stainless‐steel mesh sizes. Furthermore, the SSM 200 exhibits a low overpotential of 337 mV at a current density of 10 mA/cm 2 and a Tafel slope of 62.2 mV/decade, surpassing the performance of several previously reported electrodes for the OER. Stability tests conducted under constant voltage further confirm the remarkable stability of SSM 200, making it an ideal anode for electrolytic cell applications. These findings emphasize the cost‐effectiveness and high stability of SSM 200, presenting intriguing possibilities for future research and advancements in this field.
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