磷化氢
配位聚合物
配位几何学
配体(生物化学)
配位复合体
结晶学
聚合物
协调数
带隙
化学
材料科学
几何学
晶体结构
冶金
数学
离子
分子
金属
氢键
有机化学
光电子学
受体
生物化学
阻燃剂
作者
Soňa Ondrušová,Jan Hynek,Jan Demel,Kamil Lang,Matouš Kloda
标识
DOI:10.1016/j.jssc.2024.124806
摘要
Five coordination polymers, denoted as ICR-15, ICR-16, ICR-17, ICR-18, and ICR-19, were prepared using three previously reported phosphinic acids, namely H2PBP(Me), H2PBP(Ph), H2BBP(Me), and one new ligand H3TPBTP(Me), in conjunction with Cu2+ cations. These coordination polymers were characterized with single crystal X-ray diffraction, Fourier transform infrared (FTIR) spectroscopy, thermal analysis, and UV-vis spectroscopy. The crystal structures of the coordination polymers were analysed, revealing a variety of coordination environments and distinct structural motifs. Optical band gaps determined from the UV-vis spectra of the coordination polymers range from 2.8 eV to 3.5 eV, corresponding to wide bandgap semiconductors. Interestingly, the coordination geometry of Cu2+ was found to have a negligible influence on the size of the direct or indirect band gap.
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