反应性(心理学)
化学
喹啉
聚合
开环聚合
单体
高分子化学
分散性
背景(考古学)
己内酯
取代基
催化作用
齿合度
聚合物
药物化学
有机化学
晶体结构
医学
古生物学
替代医学
病理
生物
作者
Mengting Zang,Wenyao Cao,Xingwang Zhang,Shaofeng Liu,Zhibo Li
标识
DOI:10.1016/j.eurpolymj.2023.112103
摘要
Catalysts drive innovation in sustainable polymers because of their reactivity and selectivity. In this context, the synthesis and characterization of a series of Al complexes (Al1 − Al5) bearing N,N-bidentate amino-quinoline ligands are described, as well as their applications in ring-opening polymerization (ROP) of ε-caprolactone (ε-CL). The amido-coordination Al complexes were directly synthesized by reactions of imino-quinoline compounds with AlMe3 via methyl migration from Al to the carbon atom of imine, as indicated by both NMR spectroscopy and X-ray diffraction. In the presence of BnOH, complexes Al1 − Al5 showed significant reactivity for ROP of ε-CL with good control over molar mass (Mn) and dispersity (Đ < 1.2), and polycaprolactones (PCLs) with high molecular weights (Mn up to 129 kDa) were readily synthesized. Remarkably, immortal catalysis with excess of BnOH (up to 20 equiv. to Al) was achieved to prepare PCLs with predictable Mns, low dispersities, and end groups using an extremely low loading of Al complex (0.05 mol% to ε-CL monomer).
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