超级电容器
纳米纤维素
比表面积
材料科学
超临界干燥
气凝胶
纳米结构
电解质
超临界流体
多孔性
碳纤维
电容
化学工程
复合材料
纳米技术
化学
复合数
纤维素
电极
有机化学
催化作用
工程类
物理化学
作者
Guoqing Zu,Jun Shen,Liping Zou,Fang Wang,Xiaodong Wang,Yewen Zhang,Xiandong Yao
出处
期刊:Carbon
[Elsevier]
日期:2015-12-16
卷期号:99: 203-211
被引量:244
标识
DOI:10.1016/j.carbon.2015.11.079
摘要
High-surface-area carbon aerogels are synthesized by pyrolysis of nanocellulose aerogels that are prepared by dissolving of cellulose microcrystalline in NaOH aqueous solutions followed by gelation, regeneration and freeze drying or supercritical CO2 drying. The obtained carbon aerogels are further treated via a CO2 activation process. The result shows that the nanocellulose aerogels dried by supercritical CO2 exhibit a high specific surface area (299 m2/g) and the obtained carbon aerogels preserve the interconnected 3D nanostructure and have a high specific surface area of 892 m2/g and a high pore volume of 1.80 cm3/g, which increase to 1873 m2/g and 2.65 cm3/g respectively after CO2 activation. The highly porous and interconnected nanostructure provides efficient migration of electrolyte ions and electrons, which makes the resultant activated carbon aerogels exhibit excellent electrochemical performance for supercapacitors. The specific capacitances reach 302 and 205 F/g at a current density of 0.5 and 20 A/g respectively within a potential window of −1.0 to 0 V in 6 M KOH solution. The capacitance retains 92% after 4000 cycles of charge/discharge, implying a good cycling stability.
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