材料科学
自愈
自愈水凝胶
纳米技术
光热效应
聚乙烯醇
聚吡咯
佩多:嘘
聚氨酯
纳米棒
光热治疗
聚合物
乙烯醇
化学工程
复合材料
聚合
高分子化学
医学
替代医学
病理
工程类
作者
Lijian Xu,Yin Chen,Maolin Yu,Mengjuan Hou,Guo Gong,Haihu Tan,Na Li,Jianxiong Xu
出处
期刊:Nano Energy
[Elsevier]
日期:2022-12-26
卷期号:107: 108119-108119
被引量:74
标识
DOI:10.1016/j.nanoen.2022.108119
摘要
Flexible conductive hydrogels with self-healing ability have attracted great attention in the fields of wearable devices and healthcare monitoring due to their recoverability and sustainability. Herein, the application of inorganic antimony sulfide (Sb2S3) as photothermal agent is extended to the field of self-healing hydrogel for the first time. A near-infrared (NIR) light-induced rapid self-healing double-network conductive hydrogel (SPOH gel) via on-demand irradiation was fabricated by incorporating dopamine (DA)-modified polypyrrole (PPy) coated Sb2S3 nanorod (Sb2S3 @PPy-DA) into the polymer matrix of polyvinyl alcohol (PVA)/poly(N-(2-hydroxyethyl)acrylamide) (pHEAA) in a water-glycerol dispersion medium. The SPOH gel with adhesive and anti-freezing properties exhibited robust tensile strength (1.25 MPa), large elongation (620%), high interfacial toughness (251 J/m2), and outstanding sensitivity (GF = 4.97). The incorporation of Sb2S3 @PPy-DA for SPOH gel endowed high conductivity (2.26 S/m) and promoted rapid self-healing process under NIR light irradiation (within 90 s). Moreover, SPOH gel could be widely applied to various applications, including monitoring various human motions as strain sensor, detecting electrocardiogram signals as biopotential electrodes, and harvesting energy as self-powered device. The multifunctional SPOH gel with the integrated attractive capabilities of rapid self-reparability and real-time physiological signal detection, providing a promising route to develop wearable smart devices in motion monitoring, healthcare management, and energy harvesting applications.
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