Gold(i)-catalyzed C-glycosylation of glycosyl ortho-alkynylbenzoates: the role of the moisture sequestered by molecular sieves

C-Glycosylation of glycosyl ortho-hexynylbenzoates with allyltrimethylsilane or silyl enol ethers could proceed smoothly under the catalysis of Ph₃PAuNTf₂, wherein the moisture sequestered by the molecular sieves ensured the gold(i)-catalytic cycle.