Designing Stable Deep‐Blue Thermally Activated Delayed Fluorescence Emitters through Controlling the Intrinsic Stability of Triplet Excitons

Abstract Thermally activated delayed fluorescence (TADF) has emerged as a promising and pragmatic light‐generation method for producing efficient organic light‐emitting diodes (OLEDs). However, the low operational stability associated with blue‐light TADF emitters is a major drawback and the excited‐state molecular degradation process remains poorly understood. Archetypal TADF emitters are comprised of cycloamine donor and aromatic acceptor moieties, with the corresponding C–N bond considered as the weakest link in the molecular structure. Understanding mechanism of the C–N dissociation in the excited state is, thus, crucial to the engineering of more stable OLEDs. Here, by using a carbazole donor and a triazine acceptor with various functional groups, it is shown that the position of the triplet exciton is the key to enhancing operational stability and, therefore, device lifetime. Interestingly, repositioning the triplet exciton away from the C–N bond causes the dissociation pathway to diverge from a smooth transition state to a more abrupt conical intersection with a higher energy barrier. We realize a 2.3‐fold increase in device lifetime without compromising traditional design factors, such as the singlet–triplet energy gap, with judicious introduction of functional groups to the acceptor.