超级电容器
材料科学
循环伏安法
电化学
电极
聚苯胺
导电聚合物
化学工程
纳米技术
原位聚合
聚合
聚合物
复合材料
化学
工程类
物理化学
作者
S. Rajkumar,Elaiyappillai Elanthamilan,J. Princy Merlin,Anandaraj Sathiyan
标识
DOI:10.1016/j.jallcom.2021.159876
摘要
Abstract Conducting polymers incorporated with binary metal oxides are the upcoming pseudocapacitive materials, which are in high demand owing to their impressive electrochemical performance. In the current study, we describe the synthesis of FeCo2O4/PANI by in-situ polymerization method and its applicability as electrode in supercapacitors. The as-prepared FeCo2O4/PANI was characterized via various physico-chemical techniques. The electrochemical behavior of FeCo2O4/PANI was analysed by Cyclic voltammetry (CV), Galvanostatic charge-discharge (GCD) and Electrochemical Impedance Spectroscopic (EIS) methods. The studies revealed pronounced specific capacity (Csp) value of 940 C g−1 at the current density of 1 A g−1 by GCD. Moreover, the elevated capacitive behavior was mainly due to its very porous nanorod like structure with a huge number of active sites, which substantially resulted in good ion and electron transport. The high specific capacity of FeCo2O4/PANI and the simple one-step fabrication process depicted its potential and promising applicability as electrode material for advanced energy storage devices.
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