光催化
材料科学
纳米复合材料
异质结
制氢
分解水
氮化碳
化学工程
聚苯胺
氢
光化学
半导体
热液循环
带隙
纳米技术
光电子学
催化作用
化学
复合材料
有机化学
聚合物
工程类
聚合
作者
Monika Sindhu,Ajit Sharma,Vijaykumar G. Patel,Amika Gahalwat,Prabal Pratap Singh,Karan Singh Maan,Deepak Kumar,Van‐Huy Nguyen
标识
DOI:10.1016/j.cherd.2023.07.050
摘要
Hydrogen (H2) production in water-splitting could be significantly increased by designing cost-effective photocatalysts with remarkable performance. The main objective of this study is to recognize the behavior of soot carbon-based metal nitrides nanocomposites on its photocatalytic activity when exposed to solar lights. This study synthesized a p-n heterojunction Ta3N5/PANI composite photocatalyst modified by eco-friendly and low-cost biomass soot carbon (BSC) using hydrothermal and chemisorption methods. BSC materials are photoactive when exposed to UV light because of their band gap (Eg < 4 eV), indicating they behave as semiconductors. Compared to pure Ta3N5, the hydrogen production rate of a photocatalyst containing polyaniline (PANI) can reach up to 76.9 μmol g−1 h−1, equivalent to 3.42 times superior to pristine Ta3N5. The formation of a p-n heterojunction at the interface of PANI and Ta3N5 was primarily responsible for improving the H2 evolution activity. This successfully prevents the self-photocorrosion of Ta3N5 by providing a rapid route for the migration and separation of photogenerated charges. It also confirms the long-term stability of the materials by repeating the experiments up to 6 cycles with more than 95 %.
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