Synthesis of conjugated bisallenes by cooperative Cu/Pd-catalysed borylallenylation of 2-trifluoromethyl-1,3-enynes

We report a cooperative Cu/Pd-catalysed borylallenylation of 2-trifluoromethyl-1,3-enynes with diboron reagents and propargylic carbonates access to a series of conjugated bisallenes with excellent functional group compatibility.