Natural Solid-State Hydrogel Electrolytes Based on 3D Pure Cotton/Graphene for Supercapacitor Application

A conductive cotton hydrogel with graphene and ions can come into contact with electrodes in solid electrolytes at the molecular level, leading to a more efficient electrochemical process in supercapacitors. The inherently soft nature of cotton mixed with hydrogel provides superior flexibility of the electrolyte, which benefits the devices in gaining high flexibility. Herein, we report on the current progress in solid-state hydrogel electrolytes based on 3D pure cotton/graphene and present an overview of the future direction of research. The ionic conductivity of a complex hydrogel significantly increased by up to 13.9 × 10−3 S/cm at 25 °C, due to the presence of graphene, which increases ionic conductivity by providing a smooth pathway for the transport of charge carriers and the polymer. Furthermore, the highest specific capacitance of 327 F/g at 3 mV/s was achieved with cyclic voltammetry measurement and a galvanostatic charge–discharge measurement showed a peak value of 385.4 F/g at 100 mA/g current density. Furthermore, an electrochemical analysis demonstrated that a composite cotton/graphene-based hydrogel electrolyte is electrically stable and could be used for the design of next-generation supercapacitors.