Efficient degradation of sulfamethoxazole by the CuO@Al2O3 (EPC) coupled PMS system: Optimization, degradation pathways and toxicity evaluation

The [email protected]2O3 (EPC) (prepared by an electroless plating and calcining method) was used to activate peroxymonosulfate (PMS) for advanced oxidation of sulfamethoxazole (SMX) in deionized water, and effects of three key parameters of its all parameters (i.e., [email protected]2O3 (EPC) dosage, PMS dosage, and initial solution pH) on the [email protected]2O3 (EPC)/PMS system were studied. Under the optimal conditions (i.e., [catalyst]0 = 0.5 g/L, [PMS]0 = 0.4 mM and initial solution pH of 6.2), the SMX removal efficiency obtained by the [email protected]2O3 (EPC)/PMS process was 99%, while the SMX removal efficiency were 76% and 72% in [email protected]2O3 (IC) (prepared by an impregnation-calcination method)/PMS and CuO/PMS system respectively. Adding H2PO4− into [email protected]2O3 (EPC)/PMS system decreased the SMX removal efficiency, while the degradation efficiency was improved when Cl− was introduced the oxidation system. Furthermore, five possible degradation pathways of SMX were proposed according to the analysis results of intermediates detected by UPLC-QTOF-MS/MS. The biological toxicities of the degraded SMX solution were evaluated by activated sludge inhibition experiments. What is more, it was found that three radicals (i.e. SO4−, OH and O2−) made contributions to SMX degradation in the [email protected]2O3 (EPC)/PMS system according to radicals scavenging experiments. Residual PMS, and generated SO4− and OH radicals were quantified in [email protected]2O3 (EPC)/PMS system, and the electron paramagnetic resonance (EPR) was used to detect the generation of radicals. Finally, the mechanism of the [email protected]2O3 (EPC)/PMS system was proposed according to analysis data of XPS and radical scavenging experiments.