芳基
卤化物
镍
可扩展性
组合化学
化学
标杆管理
背景(考古学)
范围(计算机科学)
简单(哲学)
计算机科学
协议(科学)
工艺工程
有机化学
工程类
业务
程序设计语言
数据库
古生物学
营销
医学
替代医学
病理
哲学
烷基
认识论
生物
作者
Terry Shing‐Bong Lou,Yu Kawamata,Tamara El‐Hayek Ewing,Guillermo A. Correa‐Otero,Michael R. Collins,Phil S. Baran
标识
DOI:10.1002/anie.202208080
摘要
Simple access to aryl sulfinates from aryl iodides and bromides is reported using an inexpensive Ni-electrocatalytic protocol. The reaction exhibits a broad scope, uses stock solution of simple SO2 as sulfur source, and can be scaled up in batch and recycle flow settings. The limitations of this reaction are clearly shown and put into context by benchmarking with state-of-the-art Pd-based methods.
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