Optical and Morphological Properties of Single-Phased and Dual-Emissive InP/ZnS Quantum Dots via Transition Metallic and Inorganic Ions

量子点 离子 过渡金属 材料科学 纳米技术 光电子学 化学物理 化学 催化作用 生物化学 有机化学
作者
Xian Wei,Shiliang Mei,Bobo Yang,Zhihao Chen,Hanqing Dai,Zhe Hu,Guilin Zhang,Fengxian Xie,Wanlu Zhang,Ruiqian Guo
出处
期刊:Langmuir [American Chemical Society]
卷期号:36 (34): 10244-10250 被引量:15
标识
DOI:10.1021/acs.langmuir.0c01788
摘要

Single-phased and dual-emissive nanocrystals with broad emission are attractive fluorescent materials for optoelectronic devices due to their unique properties. Until now, the effect of different metallic cations and inorganic anions on III–V group quantum dots (QDs) concerning luminescence features and crystalline growth has been less explored. In this work, dual-emissive InP/ZnS QDs single-doped with transition-metal compounds (Cu2+, Ag+, or Mn2+) are synthesized to compare their optical and morphological properties. The corresponding doping concentrations to realize dual emission with comparative intensity for Cu, Ag, and Mn are 0.8, 6, and 80%, which vary greatly and might be attributed to different precursor reactivities. As for the morphological and internal structures, transmission electron microscopy (TEM) images indicate that transition-metal ions have no obvious effect on the morphological properties and a higher concentration of chloride anions binding with an In-rich interface could conduce to a homogeneous distribution and triangular growth through the comparison of different metal chlorides as precursors. X-ray photoelectron spectroscopy (XPS) results further demonstrate that the high-resolution In 3d spectrum of Mn-doped InP/ZnS QDs with MnCl2 is mainly dominated by In–P bonds, indicating fewer intermediate chemical states. These results concerning well-defined InP/ZnS QDs could promote more diverse insight into surface chemistry and help to better understand the growth mechanism, thus making it possible to regulate InP/ZnS QDs into desired formats for different practical applications like white light-emitting diodes (LEDs).
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