钙钛矿(结构)
钝化
材料科学
能量转换效率
卤化物
热稳定性
带隙
吸收边
化学工程
光电子学
纳米技术
化学
无机化学
工程类
图层(电子)
作者
Meng Qi,Yichuan Chen,Yue Yue Xiao,Junjie Sun,Xiaobo Zhang,Chang Bao Han,Hongli Gao,Yongzhe Zhang,Hui Yan
标识
DOI:10.1007/s10854-020-03029-y
摘要
The poor stability of perovskite solar cells is a crucial obstacle for its commercial applications. Here, we investigate the thermal stability of the mixed cation organic–inorganic lead halide perovskites (FAPbI3)1−xMAPb(Br3−yCly)x films and devices in air atmosphere. The results show that with the increase of heat treatment from 25 to 250 °C, the MA-perovskite decomposed into PbI2 firstly and the efficiency of corresponding solar cells reduced linearly. For the perovskite film, the increased heat treatment temperature can bring the redshift of the absorption edge leading to the decrease of band gap from 1.569 to 1.508 eV and increase of defect density from 3.87 × 1017 cm−3 to 9.03 × 1017 cm−3. However, a proper heat treatment time (10 min) at certain temperature (85 °C) can passivate defects effectively and improve the efficiency to 16.50%, realizing a 15% relative improvement of average efficiency. This work reveals a detailed thermal decomposition behavior of perovskite material and solar cells, which may provide insights into the stability of perovskite solar cells.
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