Incorporating potassium-rich waste material in a sustainable way to stabilize dispersive clay: A novel practical approach for the construction industry

微观结构 胶凝的 材料科学 固化(化学) 阳离子交换容量 絮凝作用 火山灰 复合材料 水泥 化学工程 冶金 土壤水分 环境科学 土壤科学 硅酸盐水泥 工程类
作者
Waqas Hassan,Badee Alshameri,S. Muhammad Jamil,Zain Maqsood,Abbas Haider,Arfan Shahzad
出处
期刊:Construction and Building Materials [Elsevier]
卷期号:400: 132717-132717
标识
DOI:10.1016/j.conbuildmat.2023.132717
摘要

The inappropriate use of dispersive clay in constructing roads/highways, embankments, and other structures causes significant challenges to the construction industry. The dispersive clay treatment in this work was carried out for the first time using eco-friendly and sustainable potassium-based material rather than calcium-based, which makes it particularly innovative. This study investigated the impact of potassium-rich wood ash (KRWA) on dispersion, index, unconfined compression strength (UCS), consolidation, physio-chemical, mineralogical and microstructure properties. KRWA amount varied up to 35% and cured for up to 60 days at about 20 to 25 °C. The results revealed that 10% KRWA is the optimum content, decreasing the dispersion and sodium percentage by 82% and 57%, respectively, with 28 days of curing and changing the soil class to non-dispersive. A 56% reduction in plasticity was observed with optimum content, which caused the soil to become more friable, enhancing the treated clay's workability. Moreover, a 575% raise in UCS and a 60% reduction in compressibility were witnessed, which indicates improved load-bearing capacity and the capability of the stabilized clay to bear external loads better. The physio-chemical study revealed that the ion exchange, agglomeration, and flocculation take place immediately with minor/no curing that decreased the repulsion and diffuse double layer thickness, followed by the initiation of the pozzolanic activity, which formed different cementitious gels. X-ray diffraction and scanning electron microscopy experiments confirmed the formation of gels and produced a considerably thicker microstructure. Moreover, cost-based analysis shows that KRWA is more economical than conventional additives for highway/road applications.
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