材料科学
聚苯胺
超级电容器
石墨烯
X射线光电子能谱
纳米线
电容
傅里叶变换红外光谱
电极
化学工程
石墨
扫描电子显微镜
纳米技术
箔法
水平扫描速率
电化学
循环伏安法
复合材料
化学
聚合物
物理化学
工程类
聚合
作者
Yin‐Jian Ye,Zihang Huang,Yu Song,Jin-Wang Geng,Xinxin Xu,Xiaoxia Liu
标识
DOI:10.1016/j.electacta.2017.04.025
摘要
Direct electrochemical growth of polyaniline nanowire arrays (PANI NWAs) on surfaces of graphene sheets in partially exfoliated graphite foil (Ex-GF) was achieved through electropolymerization of aniline to fabricate hierarchical nanostructured pseudocapacitive electrodes. The PANI NWAs were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). Due to the combined merits of PANI NWA and graphene sheets, the hierarchical nanostructured electrodes demonstrated high pseudocapacitive performances. More importantly, fast capacitance fading of pseudocapacitive materials upon mass loading increase can be suppressed by the novel structure, making it a good candidate for supercapacitor electrode with high areal capacitance. The PANI NWA with a high mass loading of 5.89 mg cm−2 showed an exceptionally high areal capacitance of 3.57 F cm−2 and a quite high specific capacitance 607 F g−1. 72.4% of the capacitance can be retained when the discharge current increase 10 times, demonstrating its high rate capability.
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