Elastomer-Free, Stretchable, and Conformable Silver Nanowire Conductors Enabled by Three-Dimensional Buckled Microstructures

Many three-dimensional (3D) nanomaterial-based assemblies need incorporation with elastomers to attain stretchability—that also compromises their pristine advantages for functional applications. Here, we show the design of elastomer-free, highly deformable silver nanowire (AgNW) conductors through dip-coating AgNWs on a 3D polymeric scaffold and following a simple triaxial compression approach. The resulting 3D AgNW conductors exhibit good stability of resistance under multimodal deformation, such as stretching, compressing, and bending as well as comparable conductivity with those elastomer-based ones. Moreover, the buckled structures endow our 3D conductors with novel negative Poisson’s ratio behavior, which can offer good comfortability to curvilinear surfaces. The combination of mechanical properties, conductive performance, and unique deformation characteristics can satisfy multiscale conformal mechanics with a soft, curvilinear human body.