链烷
立体中心
对映体药物
手性(物理)
纳米技术
超分子手性
化学
轴手性
超分子化学
分子
立体化学
材料科学
物理
催化作用
对映选择合成
有机化学
量子力学
手征对称破缺
Nambu–Jona Lasinio模型
夸克
作者
Ellen M. G. Jamieson,Florian Modicom,Stephen M. Goldup
摘要
Although chiral mechanically interlocked molecules (MIMs) have been synthesised and studied, enantiopure examples are relatively under-represented in the pantheon of reported catenanes and rotaxanes and the underlying chirality of the system is often even overlooked. This is changing with the advent of new applications of MIMs in catalysis, sensing and materials and the appearance of new methods to access unusual stereogenic units unique to the mechanical bond. Here we discuss the different stereogenic units that have been investigated in catenanes and rotaxanes, examples of their application, methods for assigning absolute stereochemistry and provide a perspective on future developments.
科研通智能强力驱动
Strongly Powered by AbleSci AI