双金属片
催化作用
邻苯二甲酸盐
合金
纳米颗粒
选择性
化学
催化加氢
材料科学
核化学
无机化学
有机化学
纳米技术
作者
Yao Xü,Chenguang Wu,Yan Wang,Ying Zhang,Hui Sun,Haijun Chen,Yujun Zhao
标识
DOI:10.1016/j.cclet.2020.04.016
摘要
RuPt/AC bimetallic catalysts were prepared by two-step incipient impregnation method and evaluated in the hydrogenation of phthalates. According to the characterization results, well dispersed RuPt bimetallic nanoparticles were formed on the catalyst, and the strong interaction between the two metals resulted in the formation of RuPt alloy. It was found that Ru can donate electrons to Pt on RuPt alloy nanoparticles, leading to the formation of electron-deficient Ru which significantly promotes the hydrogenation rate of dioctyl phthalate and improves the selectivity of dioctyl di-2-ethylhexylcyclohexane-1,4-dicarboxylate by accelerating the further hydrogenation of intermediate products. The bimetallic RuPt catalyst also presented excellent stability and versatility in the hydrogenation of phthalates, demonstrating its prospective future in the hydrogenation of aromatic ring contained compounds.
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