The efficiency of full-scale subsurface constructed wetlands with high hydraulic loading rates in removing pharmaceutical and personal care products from secondary effluent

Constructed wetlands (CWs) are usually operated at low hydraulic load rates (HLRs) of < 0.5 m3/m2/d, and can efficiently remove pharmaceuticals and personal care products (PPCPs) from wastewaters. They however often occupy a large area of land, especially when treating the secondary effluent from wastewater treatment plants (WWTPs) in megacities. High-load CWs (HCWs) with an HLR ≥ 1 m3/m2/d, requiring smaller land areas, are a good option for urban areas. However, their performance for PPCP removal is not clear. In this study, we evaluated the performance of three full-scale HCWs (HLR: 1.0-1.3 m3/m2/d) to remove 60 PPCPs, and found they had a stable removal performance and a higher areal removal capacity than the previously reported CWs operated at low HLRs. We verified the advantages of HCWs by testing the efficiency of two identical CWs at a low HLR (0.15 m3/m2/d) and a high HLR (1.3 m3/m2/d) fed with the same secondary effluent. The areal removal capacity during the high-HLR operation was 6-9 times higher than that during the low-HLR operation. A high dissolved oxygen content, and low COD and NH4-N concentrations in the secondary effluent were critical for the robust PPCP removal by tertiary treatment HCWs.