超分子化学
自组装
材料科学
纳米技术
结晶学
化学
晶体结构
作者
Ke Li,Kai-Ling Zhu,Liping Cui,Jiajia Chen
出处
期刊:Dalton Transactions
[The Royal Society of Chemistry]
日期:2023-01-01
卷期号:52 (42): 15168-15177
被引量:3
摘要
Giant polyoxomolybdates are a special class of polyoxometalate clusters which can bridge the gap between small molecule clusters and large polymeric entities. Besides, giant polyoxomolybdates also show interesting applications in catalysis, biochemistry, photovoltaic and electronic devices, and other fields. Revealing the evolution route of the reducing species into the final cluster structure and also their further hierarchical self-assembly behaviour is undoubtedly fascinating, aiming to guide the design and synthesis. Herein, we reviewed the self-assembly mechanism study of giant polyoxomolybdate clusters, and the exploration of a new structure and new synthesis methodology is also summarized. Finally, we emphasize the importance of in-operando characterization in revealing the self-assembly mechanism of giant polyoxomolybdates, and especially for the further reconstruction of intermediates into the designable synthesis of new structures.
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