环氧树脂
固化(化学)
聚丙烯
材料科学
极限抗拉强度
缩水甘油醚
复合材料
热固性聚合物
异氰酸酯
支化(高分子化学)
高分子化学
胺气处理
双酚A
乙醚
化学
有机化学
聚氨酯
作者
Raj Kumar,Mahmad Ziya Gous,Raviteja Surakasi,K. S. Raghuram,Prashant Sunagar,Neelam Sanjeev Kumar,Anand Kumar Pandey,S. Padmavathy,M. Sudhakar,S. Praveen Kumar
摘要
Temperature-sensitive cure kinetics based on bisphenol A oligomeric diglycidyl ether and branching diphenylmethane di-isocyanate, polymer aliphatic or lower molecular weight aromatic amines, and polypropylene and epoxy composites were examined. Polypropylene networks are formed initially, followed by amine hardeners interfering with epoxy oxirane rings to frame linear oligomers. Finally, the system is formed by a reaction between amines obtained in the second phase and epoxy oxirane rings during the curing step. This three-stage treatment was illustrated. The activation energy was calculated using the Flynn-Wall-Ozawa and Kissinger-Akahira-Sunose isoconversational approaches to cure degree. The Ea-to- correlation was determined using these approaches, revealing that the research curing systems exhibited autocatalytic effects. Among the materials studied, compounds with low molecular weight aromatic amines had the strongest and longest-lasting tensile characteristics. There are numerous advantages to slow curing and discrete stages of composite creation, including better mechanical properties.
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