过电位
镍
塔菲尔方程
硫黄
催化作用
硫化物
硫化镍
硫化氢
无机化学
交换电流密度
电化学
制氢
化学
材料科学
电极
有机化学
物理化学
作者
Zhiqiang Fang,Yuqing Wang,Yizhen Zou,Zhaomin Hao,Qingsong Dong
标识
DOI:10.1016/j.inoche.2016.12.010
摘要
Among low-cost and earth-abundant elements, the nickel-based HER catalysts, particularly nickel sulfide, are considered as one of the most promising candidates in this field. In this paper, a kind of spherical nickel sulfide material was obtained using nickel acetate and sulfur powder as precursors by one-pot synthesis. The use of sulfur powder as sulfur source with solution-based method will enable the synthesis of metal sulfides to be more simple and capable of mass production. In addition, the as-synthesized nickel sulfide exhibits an onset overpotential of as low as 25 mV, a Tafel slope of 90 mV dec− 1, and an exchange current density of 0.44 mA cm− 2. Furthermore, this catalyst maintains its catalytic activity for at least 25 h and only requires overpotentials of 42 and 113 mV to attain current densities of 2 and 10 mA cm− 2, respectively. The electrocatalytic performance is promising for applications as non-noble-metal HER catalyst with water splitting for hydrogen production.
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