Chitosan-assisted MOFs dispersion via covalent bonding interaction toward highly efficient removal of heavy metal ions from wastewater

Metal organic frameworks (MOFs) have been considered to be robust adsorbent for the removing heavy metal ions from wastewater due to their unique properties such as large active sites, high specific surface area and high porosity, etc., however, their practical engineering application faces the problem of serious agglomeration. In this work, a new strategy of chitosan (CS) assisting MOF dispersion was proposed to develop the new generation of MOF-based adsorbents, namely, CS grafted UiO-66-NH2 composite materials (CGUNCM). The UiO-66-NH2 was selected and it was grafted onto the main chains of CS through covalent bonding interaction with the aid of glutaraldehyde, which was totally different from the common method that grafting molecular chains on the surface of MOFs resulting in the dramatic reduction of active adsorption sites. The results show that grafting MOFs onto CS main chains not only greatly improves the dispersion of MOFs but also reserves the morphology of MOFs as much as possible. The adsorption performances toward Cu(II) and Pb(II) were intensively studied by varying adsorbate concentration, ionic strength, the contact time, adsorption temperature and pH value of solution. The results show that the composite adsorbent exhibits high adsorption efficiency and the adsorption equilibrium can be reached within 45 min, and the maximum adsorption capacity toward Cu(II) and Pb(II) achieve 364.96 mg/g and 555.56 mg/g, respectively. Furthermore, the composite adsorbent shows good reusability. This work provides a new method of fabricating the MOF-based adsorbent and paves the way for the practical application of such adsorbents in wastewater treatment.