Continuous and selective copper recovery by multi-modified and granulated SBA-15

Continuous and selective recovery of copper (Cu) from heavy metal wastewater not only mitigates the pollution of environment but also can be applied for industrial field. Due to several advantages such as large pore size, easy modification, physical and chemical stabilities, mesoporous silica material, SBA-15, has been synthesized via hydrothermal reaction in this study. For enhancing the adsorption capacity and selectivity for Cu ions, prepared SBA-15 was modified with manganese loading and amine-grafting (MN-SBA) then granulated by alginic-acid (GMN-SBA), successfully. Adsorption capacities for heavy metals such as Cu, Zn, Ni and Mn were 2.11, 1.24, 1.74 and 1.25 mmol/g on MN-SBA and decreased to 1.23, 0.68, 0.86 and 0.65 when it was granulated. Even though the adsorption capacities of GMN-SBA for heavy metals decreased by 40–50%, it enabled easy regeneration and separation process when applied for continuous fixed-bed column adsorption mode. Specifically, the results demonstrated that GMN-SBA was able to be reused for 5 times while maintaining over 80% adsorption capacities. Fixed-bed adsorption results were well explained by dynamic adsorption model incorporated with linear driving force approximation (LDFA) model. The simulation of fixed-bed adsorption tests was proceeded in terms of bed length, feeding concentration and flow rate, and it showed the breakthrough times were shifted in the axis of time. In multi-component adsorption, LDFA model showed a high overshoot phenomenon of the breakthrough curves for Zn, Ni and Mn compared to Cu. This reflected the high affinity of Cu towards GMN-SBA compared to other heavy metals. • Synthesized SBA-15 was well modified by Mn loading and amine grafting methods. • Granulation of modified SBA-15 was successfully carried out. • Prepared adsorbent enabled to maintain 80% of Cu recovery for cyclic experiments. • Batch heavy metal adsorption experiments were described well by adsorption models. • Fixed-bed adsorption tests were conducted and explained well by dynamic model.