Internal electric fields drive dual S-scheme heterojunctions: Insights into the role of the triple interlaced lattice

The internal electric field induced by the lattice interfaces in a heterojunction can facilitate charge transfer, thereby improving the photocatalytic performance. However, the details of the relationship between the lattice interfaces and the charge transfer mechanism in heterojunctions remain unclear. In this study, a Bi2WO6/Bi2O2CO3/C3N4 heterojunction (BBC) with an interlaced lattice was prepared, and the role of the interlaced lattice in charge transfer was revealed. Compared to pristine Bi2O2CO3, Bi2WO6, and C3N4, BBC exhibited an increased ciprofloxacin degradation rate constant (0.0573 min−1). A series of experiments were performed to reveal the role of the interlaced lattice interface in the enhanced photocatalytic performance. The results show that the driving force provided by the interlaced lattice interface changes the charge transfer mechanism from a dual Ⅱ-scheme to a dual S-scheme. This work provides profound insights into the effects of lattice interfaces in heterojunctions and the design of efficient photocatalysts.