Random Copolymer Hydrogel as Elastic Binder for the SiOx Microparticle Anode in Lithium-Ion Batteries

Silicon suboxides (SiOx) have been widely concerned as a practical anode material for the next-generation lithium-ion batteries due to their relatively high theoretical capacity and lower volume change compared to silicon (Si). Nevertheless, traditional binder poly(vinylidene difluoride) (PVDF) still cannot hold the integrity of the SiOx particle due to its weak van der Waals force. Herein, a copolymer binder for SiOx microparticles is synthesized through a facile method of free radical polymerization between acrylamide (AM) and acrylic acid (AA). By adjusting the mass ratio of the AM/AA monomer, the copolymer binder can generate a covalent-noncovalent network with superior elastic properties from the synergistic effect. During electrochemical testing, the SiOx anode with the optimal copolymer binder (AM/AA = 3:1) delivered a reversible capacity of 734 mAh g-1 (two times that of commercial graphite) at 0.5C after 300 cycles. Thus, this work developed a green and effective strategy for synthesizing a water-soluble binder for Si-based anodes.