An efficient glucose sensor thermally calcined from copper-organic coordination cages

Due to the harmfulness of diabetes, a fast and efficient glucose detector is particularly important. Metal-organic polyhedron (MOP) provides a porous framework and a special matrix, which makes it an excellent precursor for electrochemical detection. Herein, we report a novel MOP as a precursor for the preparation of an electrocatalytic detector for glucose. The new metal-organic polyhedron of Cu4(TPDC)4 can be solvothermally obtained and characterized by X-ray crystallography, which can be thermally converted into nanosized copper oxides embedded into graphitic carbon layers (MOP-CO). The as-prepared MOP-CO electrode is further applied to glucose detection, which shows a fast response time (<1 s) in a wide linear range of 0-4000 μM and high sensitivity of 2720 μA mM-1 cm-2, as well as low detection limit (26 nM (S/N = 3)), good anti-interference, repeatability and stability (>3600 s).