Carbon capture for blackwater: chemical enhanced high-rate activated sludge process

Abstract Blackwater has more benefits for carbon recovery than conventional domestic wastewater. Carbon capture and up-concentration are crucial prerequisites for carbon recovery from blackwater, the same as domestic wastewater. Both chemical enhanced primary treatment (CEPT) and high-rate activated sludge (HRAS) processes have enormous potential to capture organics. However, single CEPT is subject to the disruption of influent sulfide, and single HRAS has insufficient flocculation capacity. As a result, their carbon capture efficiencies are low. By combining CEPT and HRAS with chemical enhanced high rate activated sludge (CEHRAS) process, the limitations of single CEPT and single HRAS offset each other. The carbon mineralization efficiency was significantly influenced by SRT rather than iron salt dosage. An iron dosage significantly decreased chemical oxygen demand (COD) lost in effluent. Both SRT and iron dosage had a significant influence on the carbon capture efficiency. However, HRT had no great impact on the organic mass balance. CEHRAS allowed up to 78.2% of carbon capture efficiency under the best conditions. The results of techno-economic analysis show that decreasing the iron salt dosage to 10 mg Fe/L could promise profiting for blackwater treatment. In conclusion, CEHRAS is a more appropriate technology to capture carbon in blackwater.