聚氨酯
点击化学
弹性体
聚己内酯
二醇
动态共价化学
二硫键
二硫键
Diels-Alder反应
高分子化学
聚合物
共价键
材料科学
化学
有机化学
分子
复合材料
半胱氨酸
催化作用
酶
超分子化学
生物化学
作者
Prasanta Kumar Behera,Sagar Kumar Raut,Prantik Mondal,Shrabana Sarkar,Nikhil K. Singha
出处
期刊:ACS applied polymer materials
[American Chemical Society]
日期:2021-01-11
卷期号:3 (2): 847-856
被引量:61
标识
DOI:10.1021/acsapm.0c01179
摘要
Functional polyurethanes have several important advanced applications. In this investigation, a dual-functional polyurethane (PU) elastomer having disulfide as well as furfuryl functionality was developed. For this purpose, a functional diol having furfuryl and disulfide functionality was synthesized and used as a chain extender for the synthesis of a PU elastomer based on polycaprolactone (PCL) diol and 4,4′-methylenebis (phenyl diisocyanate) (MDI). This dual functional PU elastomer was cross-linked using a bismaleimide (BM) via the Diels–Alder (DA) reaction with the furfuryl pendant group in PU. This dual functional PU having thermoreversible DA linkage and disulfide linkage showed excellent tensile strength (σ = 39.5 MPa) and, importantly, good self-healing characteristics (self-healing efficiency, Eσ ≈ 97%). This healable PU having a thermoresponsive as well as a double dynamic covalent system based on the DA reaction and the disulfide metathesis reaction will have potential applications in specialty paints, coatings, and various advanced materials.
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