腐蚀
缓蚀剂
傅里叶变换红外光谱
环境友好型
X射线光电子能谱
极化(电化学)
电化学
金属
吸附
化学
材料科学
高效液相色谱法
核化学
化学工程
冶金
色谱法
有机化学
物理化学
生态学
生物
电极
工程类
作者
Qihui Wang,Qi Zhang,Huahao Zheng,Li Liu,Xiaodi Wu,Chongkang Zhao,Xing Zhou,Yi Sun,Zhitao Yan,Xueming Li
标识
DOI:10.1016/j.scp.2023.101177
摘要
In this study, corrosion inhibitors from waste protein were extracted, and their anti–corrosion behavior was investigated on a laboratory–scale. The functional groups of the protein waste extract (PWE) were identified using Fourier transform infrared (FTIR) spectroscopy. High–performance liquid chromatography (HPLC) was used to determine the variety and concentration of the amino acids. The efficiency of the inhibitor was assessed by electrochemical experiments. The results show that PWE, as an environmentally friendly corrosion inhibitor, has the highest corrosion inhibition efficiency of up to 96.2% at a temperature of 298 K and a concentration of 1000 ppm. The mechanism of PWE was evaluated by atomic force microscopy (AFM) and X–ray photoelectron spectrometry (XPS). The findings demonstrated that the PWE contains 17 different types of amino acids that can effectively adsorb onto the metal and inhibit the corrosion reaction of steel in an acidic environment. The polarization curve confirmed that the PWE was a mixed type of inhibitor. This work could provide useful insights into the development and utilization of eco–friendly corrosion inhibitors.
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