分子印迹聚合物
检出限
微分脉冲伏安法
电化学气体传感器
电化学
磺胺嘧啶
核化学
化学
电极
色谱法
材料科学
循环伏安法
选择性
有机化学
生物化学
抗生素
物理化学
催化作用
作者
Xifeng Yu,Jing Wang,Qirui Shen,Yue Sun,Qi Kang,Dazhong Shen
出处
期刊:Food Chemistry
[Elsevier]
日期:2024-02-01
卷期号:434: 137461-137461
被引量:10
标识
DOI:10.1016/j.foodchem.2023.137461
摘要
Herein, we report a novel differential ratiometric molecularly imprinted polymer (MIP) electrochemical sensor for sulfadiazine (SDZ). An MIP membrane with double templates, SDZ and propyl gallate (PG), was fabricated on glassy carbon electrode (GCE) modified by CuInS2/ZnS nanocomposites. After adding PG in the samples as the reference, the current differences between MIP@CuInS2/ZnS/GCE and non-imprinted polymer@CuInS2/ZnS/GCE at the potentials of 0.18 V (ΔIPG) and 0.92 V (ΔISDZ) were measured. The ratio of ΔISDZ/ΔIPG was used for SDZ determination in the differential and ratiometric dual-mode. The influence of the variations in electrode modification and sample enrichment conditions on the determination of SDZ can be suppressed by 2.8 ∼ 13.2-fold, enhancing the reproducibility and stability of the MIP sensor. The interference level was reduced by one order of magnitude compared with the normal MIP mode. The proposed sensors were used to determine SDZ in food samples, with the detection limit of 2.1 nM.
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