Single-pulse shock tube pyrolysis of toluene and 1,3-butadiene

The objective of this research is to investigate the rate limiting chemical mechanisms leading to the formation of soot precursors. A single-pulse shock tube is being used to collect gas samples of stable intermediates and end products of hydrocarbon pyrolysis. These gas samples are analyzed quantitatively using gas chromatography and any mass imbalance is believed to be due to the formation of PAH's and soot. Experimental decomposition rates of the parent hydrocarbon are determined and compared to predictions from the literature. Detailed chemical kinetic mechanisms describing hydrocarbon pyrolysis are being developed and models of soot formation are being compared with the experimental results. Information developed from these pyrolysis studies will provide the fundamental understanding for modeling subsequent oxidation experiments.