A feasible biochar derived from biogas residue and its application in the efficient adsorption of tetracycline from an aqueous solution

The recovery of carbon materials from biogas residue (BR) could efficiently promote the efficient utilization of waste and the preparation of novel materials. In this study, a green and feasible reagent of citric acid was introduced and applied in the modification of biogas residue biochar (BRC). The modified biogas residue biochar (CABRC) showed a superior adsorption ability due to its higher specific surface area (approximately 6 times that of the BRC). Additionally, the adsorption capacities of CABRC and BRC for TC were 58.25 mg/g and 20.77 mg/g, respectively, while the TC adsorption performance of CABRC was 2.8 times that of BRC. The adsorption of TC by both BRC and CABRC was primarily controlled by physical adsorption and chemical adsorption (including pore filling, hydrogen bonding, π-π DEA interaction, and electrostatic interaction). Therefore, CABRC should be considered an environmentally friendly material due to its higher adsorption performance, which could expand its application in wastewater treatment.