Advancement in utilization of bio-based materials including cellulose, lignin, chitosan for bio-inspired surface coatings with special wetting behavior: A review on fabrication and applications

Natural bio-material surface with hydrophobic behavior (aqueous droplet to roll off from its surface) has inspired researchers to design sustainable artificial coatings with hydrophobic or superhydrophobic behavior. The developed hydrophobic or superhydrophobic artificial coatings are highly useful in various applications such as water remediation, oil/water separation, self-cleaning, anti-fouling, anti-corrosion and also in medical fields including anti-viral, anti-bacterial efficacy. In recent years, among various coating materials, bio-based materials derived from plants and animals (cellulose, lignin, sugarcane bagasse, peanut shell, rice husk, egg cell etc.) are applied on various surfaces in order to develop fluorine free hydrophobic coatings with longer durability by lowering the surface energy and increasing the surface roughness. This review summarized recent developments in hydrophobic/superhydrophobic coating fabrication methods, properties and applications with the use of different bio-based materials and their combinations. In addition, basic mechanisms behind the coating fabrication process and their durability under different environmental conditions are also discussed. Moreover, prospects and limitations of bio-based coatings in practical applications have been highlighted.