Precise Regulation of Multiple Resonance Distribution Regions of a B,N‐Embedded Polycyclic Aromatic Hydrocarbon to Customize Its BT2020 Green Emission

Abstract Recently, boron (B)/nitrogen (N)‐embedded polycyclic aromatic hydrocarbons (PAHs), characterized by multiple resonances (MR), have attracted significant attention owing to their remarkable features of efficient narrowband emissions with small full width at half maxima (FWHMs). However, developing ultra‐narrowband pure‐green emitters that comply with the Broadcast Service Television 2020 (BT2020) standard remains challenging. Precise regulation of the MR distribution regions allows simultaneously achieving the emission maximum, FWHM value, and spectral shape that satisfy the BT2020 standard. The proof‐of‐concept molecule TPABO‐DICz exhibited ultrapure green emission with a dominant peak at 515 nm, an extremely small FWHM of 17 nm, and Commission Internationale de l′Eclairage (CIE) coordinates of (0.17, 0.76). The corresponding bottom‐emitting organic light‐emitting diode (OLED) exhibited a remarkably high CIEy value (0.74) and maximum external quantum efficiency (25.8 %). Notably, the top‐emitting OLED achieved nearly BT2020 green color (CIE: 0.14, 0.79) and exhibited a state‐of‐the‐art maximum current efficiency of 226.4 cd A −1 , thus fully confirming the effectiveness of the above strategy.