双金属
发光
信号(编程语言)
天线(收音机)
调性
材料科学
光电子学
共发射极
离子
化学
计算机科学
电信
复合材料
艺术
音乐剧
视觉艺术
程序设计语言
有机化学
作者
Sameera Sh. Mohammed Ameen,Khalid M. Omer
出处
期刊:ACS materials letters
[American Chemical Society]
日期:2024-05-14
卷期号:6 (6): 2339-2349
被引量:18
标识
DOI:10.1021/acsmaterialslett.4c00845
摘要
The construction of a highly luminescent, stable, and target-insensitive internal reference signal is highly significant in ratiometric and color tonality applications. Improvement of the antenna effect, the efficient mechanism that enhances luminescence emission via sensitization, is an effective route to obtain bright luminescence. Additionally, manipulation of the crystal structure and morphology is the key issue to control the reactivity, especially in metal–organic frameworks (MOFs). In the present work, a novel internal reference red emitter of Eu/Zn bimetal biligand MOF (UoZ-5) was synthesized and used as an internal reference signal. A dual-antenna effect, from triplet states (T1) of the ligands to 5Do of the Eu3+ ion, was observed and explained on the basis of the energy levels. With UoZ-5 serving as the internal reference, blue-emitting carbon quantum dots (CQDs) selective for Ag+ ions and a nonfluorescent composite, CQDs@Ag+, serving as a selective probe for vitamin B1, a color tonality-based platform and ratiometric analysis were developed.
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