超级电容器
材料科学
电容
弯曲
电极
复合材料
复合数
储能
纳米技术
准固态
氧化石墨
石墨
电解质
功率(物理)
物理化学
化学
物理
量子力学
色素敏化染料
作者
Weigu Li,Xiaobin Xu,Chang Liu,Marshall C. Tekell,Jing Ning,Jianhe Guo,Jincheng Zhang,Donglei Fan
标识
DOI:10.1002/adfm.201702738
摘要
Abstract Flexible energy storage devices play a pivotal role in realizing the full potential of flexible electronics. This work presents high‐performance, all‐solid‐state, flexible supercapacitors by employing an innovative multilevel porous graphite foam (MPG). MPGs exhibit superior properties, such as large specific surface area, high electric conductivity, low mass density, high loading efficiency of pseudocapacitive materials, and controlled corrugations for accommodating mechanical strains. When loaded with pseudocapacitive manganese oxide (Mn 3 O 4 ), the MPG/Mn 3 O 4 (MPGM) composites achieve a specific capacitance of 538 F g −1 (1 mV s −1 ) and 260 F g −1 (1 mV s −1 ) based on the mass of pure Mn 3 O 4 and entire electrode composite, respectively. Both are among the best of Mn 3 O 4 ‐based supercapacitors. The MPGM is mechanically robust and can go through 1000 mechanical bending cycles with only 1.5% change in electric resistance. When integrated as all‐solid‐state symmetric supercapacitors, they offer a full cell specific capacitance as high as 53 F g −1 based on the entire electrode and retain 80% of capacitance after 1000 continuous mechanical bending cycles. Furthermore, the all‐solid‐state flexible supercapacitors are incorporated with strain sensors into self‐powered flexible devices for detection of both coarse and fine motions on human skins, i.e., those from finger bending and heart beating.
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