化学
超分子化学
结晶学
配体(生物化学)
圆二色性
反铁磁性
对映体药物
立体化学
喹喔啉
分子间力
晶体结构
分子
对映选择合成
有机化学
催化作用
物理
生物化学
受体
凝聚态物理
作者
Qi Yue,Huang Qiong,Yi-Yun Gao,En‐Qing Gao
标识
DOI:10.1016/j.ica.2015.12.023
摘要
Utilizing the mixed-ligand strategy, six new homochiral coordination polymers based on enantiopure (1R,2R)-1,2-cyclohexanedicarboxylic acid and varied auxiliary bipyridyl ligands, [Zn3(L)2(OH)2] (1), [Cu3(HL)2(L)2(bpy)3]·4H2O (2), [M(L)(bpe)2(H2O)2]·H2O (M = Co, 3; Ni, 4; Cd, 5), [Ni(L)(bpa)(H2O)3]·2H2O (6), [H2L = (1R,2R)-1,2-cyclohexanedicarboxylic acid, bpy = 4,4′-bipyridine, bpe = 1,2-bis(4-pyridyl)ethylene, bpa = 1,2-bis(4-pyridyl)ethane] have been hydrothermally synthesized. Compound 1 shows a 2D 63-hcb network in the absence of any bipyridyl ligand. Compound 2 is a 2D (4,4)-connected grid network in the presence of bpy. Compounds 3–5 are isomorphous and feature 1D staggered-sculls chains by using bpe instead of bpy. Compound 6 possesses a 1D left-handed helical chain sustained by flexible bpa ligand. Each type of these coordination structures is further extended into 3D supramolecular frameworks through different intermolecular interactions. Solid-state circular dichroism (CD) spectra of compounds 1–6 exhibit strong CD signals. Magnetic susceptibility measurement indicates weak antiferromagnetic interactions between the Cu(II) ions in compound 2. Compound 5 displays a strong fluorescent emission at 413 nm in solid state at room temperature.
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