Heat-activated persulfate for the degradation of micropollutants in water: A comprehensive review and future perspectives

This work is a critical review of the most important studies that have dealt with heat-activated persulfate to degrade persistent micropollutants in the last six years. The effect of the different operating parameters is discussed, wherein in all cases, the efficiency was favored at higher temperatures and oxidant concentrations. Particular emphasis was given to the effect of the aqueous matrix. Since heat activation is a homogeneous process based on the production of free radicals, in most of the studies presented, the removal of pollutants decreases as the complexity of the aqueous matrix increases except in cases where secondary oxidative species are produced that are selective with specific pollutants. It has also been observed that the change in toxicity usually follows the removal of the parent compound despite the formation of several by-products. Nowadays, combining different processes for the simultaneous activation of persulfate seems to be gaining ground. A hybrid process is an interesting strategy to reduce costs and increase efficiency, especially in real wastewater. In this light, the most interesting studies of hybrid systems for the destruction of micropollutants in recent years based on thermally activated persulfate are also summarized. Finally, some steps are proposed for future research towards the industrial application, including the study of chemical mixtures, the integrated toxicity assessment, the examination of simultaneous disinfection and decomposition of pollutants into real wastewater, the estimation of the required costs, and energy the combination of processes and their coupling with renewable sources, and the design of pilot plants and the scale-up of the hybrid processes.