Non-fused Polymerized Small-Molecule Acceptors with a Benzothiadiazole Core for All-Polymer Solar Cells

Polymerized small-molecule acceptors (PSMAs) have made significant progress as the application in all-polymer solar cells (all-PSCs). Most PSMAs are constructed by near-infrared fused-ring electron acceptors via Stille polymerization, such as Y-series acceptors. However, very limited non-fused electron acceptors with simplified synthetic complexity have been used in PSMAs. In this work, two non-fused PSMAs with a benzothiadiazole (BT) core are developed for application in all-PSCs. The S–O non-covalent interaction and the regioregularity have been introduced to improve the crystallinity and charge transport properties. As a result, a high-power conversion efficiency (PCE) of 11.42% with an enhanced photocurrent has been obtained in these regioregular PBTO-γ-based solar cells, representing the highest PCEs based on non-fused PSMAs. The encouraging results will intrigue more design of non-fused PSMAs toward high-performance all-PSCs.