电化学
材料科学
锂(药物)
介孔材料
阴极
离子
化学工程
同种类的
电导率
表征(材料科学)
纳米技术
电极
化学
催化作用
物理化学
物理
工程类
内分泌学
热力学
有机化学
医学
生物化学
作者
Yuanchao Li,Baoyan Xing,Huishuang Zhang,Mengjie Wang,Yang Li,Guangri Xu,Shuting Yang
出处
期刊:RSC Advances
[The Royal Society of Chemistry]
日期:2022-01-01
卷期号:12 (40): 26070-26077
被引量:7
摘要
Iron (Fe) substitution is an effective strategy for improving the electrochemical performance of LiMnPO4 which has poor conductivity. Herein, we focus on investigating the effect of substitution of Mn with different iron sources, on the structure and electrochemical performances of the LiMnPO4 materials. The Fe-substituted LiMnPO4/C composites were synthesized via a simple and rational solid-state method, and will be of benefit for engineering applications. The characterization of the materials shows an obvious influence of the iron sources on structure and morphology. The N-LMFP material prepared using soluble FeNO3 as iron sources exhibits an excellent rate capacity of 122 mA h g-1 at 5C, and superior cyclability with a capacity retention of 98.9% after 400 cycles at 2C. The enhanced rate capability and cycling stability of N-LMFP are the result of the lowered electron/ion resistance and the improved reversibility of the reaction, that originates from the homogeneous fine particles and hierarchical structure with large mesopores. This research provides significant guidelines for designing an LiMnPO4 cathode with a high performance.
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