超级电容器
碳纤维
热解
杂原子
材料科学
电容
电化学
化学工程
复合数
介孔材料
碱金属
氮气
稻草
多孔性
比表面积
化学
无机化学
复合材料
催化作用
电极
有机化学
戒指(化学)
物理化学
工程类
作者
Yinglin Song,Jinxiong Wu,Zheng Jiliang,Yiwei Sun,Andrei Ivanets,Guangming Du,Xintai Su
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2022-05-01
卷期号:169 (5): 053505-053505
被引量:4
标识
DOI:10.1149/1945-7111/ac6e8a
摘要
The doping of multiple heteroatoms can improve the electrochemical properties of carbon substrates. However, in existing studies, carbon, iron and nitrogen sources are generally mixed directly and then pyrolyzed for secondary activation. This tends to form aggregates of metal particles or metal oxides and requires the consumption of large amounts of alkali and energy. Therefore, there is an urgent need to develop an environmentally friendly technology capable of uniformly doping iron and nitrogen into carbon materials. In this work, porous Fe–N–C composites were prepared at 600 °C using potassium humate (HA-K) obtained from cotton straw by low-temperature pyrolysis as the carbon source, and urea-iron complexes formed by the pre-coordination of urea and Fe as the iron and nitrogen sources. In the absence of secondary activation, the best sample Fe-NHPC-2 had a good mesoporous structure with high specific surface area (889. 01 m 2 g −1 ). It had a high specific capacitance of 256.8 F g −1 at a current density of 0.5 A g −1 . The capacitance retention was 92.6% after 10,000 cycles at a current density of 10 A g −1 . In the symmetric supercapacitor application, the energy density reached 33.16 Wh kg −1 when the power density was 600.2 W kg −1 .
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