过电位
电催化剂
析氧
兴奋剂
化学工程
材料科学
氧气
纳米技术
铜
催化作用
化学
电化学
电极
物理化学
有机化学
冶金
光电子学
工程类
作者
Xiaoli Xiong,Chaoqun You,Zhiang Liu,Abdullah M. Asiri,Xuping Sun
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2018-01-29
卷期号:6 (3): 2883-2887
被引量:288
标识
DOI:10.1021/acssuschemeng.7b03752
摘要
It is highly desired to enhance the catalytic activity of oxygen evolution reaction (OER) electrocatalysts made of earth-abundant elements. In this Letter, we report that the OER activity of a CuO nanoarray can be largely enhanced by Co doping. In 1.0 M KOH, the Co-CuO nanoarray on copper foam requires a current densities of 50 and 100 mA cm–2 at overpotentials of only 299 and 330 mV, respectively. It also shows superior long-term durability over 15 h with a turnover frequency of 0.056 mol O2 s–1 at an overpotential of 300 mV.
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