材料科学
钙钛矿(结构)
卤化物
红外线的
商业化
位阻效应
二极管
光电子学
有机发光二极管
发光二极管
离子
金属
纳米技术
化学工程
无机化学
光学
化学
有机化学
业务
营销
工程类
冶金
物理
图层(电子)
作者
Qiangqiang Wang,Shuo Ding,S.S. He,Ting Zhang,Lei Qian,Peng Xiao,Tao Chen,Chaoyu Xiang
标识
DOI:10.1002/adom.202201778
摘要
Abstract Although organic metal halide perovskite light‐emitting diodes (PeLEDs) have been developed rapidly in recent years, their commercialization and further applications are still hindered by ion migration‐induced inferior operational stability. Although the formation of a quasi‐2D structure is a well‐known solution that can efficiently suppress ion migration, the operation lifetime improvement is still limited. In this study, long‐chain phenylbutanammonium is used to replace the commonly used phenethylammonium as the L‐site cations. With large steric hindrance, ion migration inside the PeLEDs is effectively suppressed. Consequently, the PeLED with near‐infrared emission at 763 nm exhibited an operational lifetime ( T 90 ) of up to 5.3 h, which is 53‐fold higher than that of the control device. This study demonstrates the feasibility of significant stability improvement using a simple cation engineering strategy for PeLEDs.
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