锂(药物)
参比电极
标准氢电极
标准电极电位
电极
电极电位
材料科学
氧化还原
可逆氢电极
钯氢电极
快离子导体
绝对电极电位
相(物质)
无机化学
化学
电解质
物理化学
医学
内分泌学
有机化学
作者
A. L. Santhosha,Lukas Medenbach,Johannes Buchheim,Philipp Adelhelm
标识
DOI:10.1002/batt.201800149
摘要
Abstract Lithium solid‐state batteries (Li‐SSBs) require electrodes that provide a sufficiently stable interface with the solid electrolyte. Due to the often limited stability window of solid electrolytes, researchers frequently favor an In−Li alloy instead of lithium metal as counter electrode for two‐electrode measurements. Maintaining a stable potential at the counter electrode is especially important because three‐electrode measurements are hard to realize in solid‐state cells. Although a constant potential of about 0.6 V vs. Li + /Li is commonly accepted for the In−Li electrode, only little is known about the behavior of this electrode. Moreover, the In−Li phase diagram is complex containing several intermetallic phases/compounds such as the InLi phase, or line compounds such as In 4 Li 5 or In 2 Li 3 . This means that the redox potential of the In−Li electrode depends on the alloy composition, i. e. the In/Li ratio. Here, we study the behavior of In−Li electrodes in cells with liquid electrolyte to determine their phase evolution and several equilibrium potentials vs. Li + /Li. The room temperature equilibrium redox potential of the In−Li electrode with the favored composition (or more precisely the Li + /(In−InLi) electrode) is 0.62 V vs. Li + /Li. We then discuss the use of In−Li electrodes in solid state cells using Li 3 PS 4 as solid electrolyte and give examples on the importance of the right In/Li ratio of the electrode. While the right In/Li ratio enables stable lithium insertion/deinsertion in symmetrical cells for at least 100 cycles, too much lithium in the electrode leads to a drop in redox potential combined with a rapid build‐up of interface resistance.
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