催化作用
化学
电催化剂
钌
选择性
电化学
吸附
5-羟甲基糠醛
无机化学
有机化学
物理化学
电极
作者
Xinyu Chai,Kaiyue Jiang,Jianying Wang,Zhouhong Ren,Xi Liu,Liwei Chen,Xiaodong Zhuang,Tianfu Wang
出处
期刊:Chemsuschem
[Wiley]
日期:2022-07-06
卷期号:15 (16)
被引量:6
标识
DOI:10.1002/cssc.202200863
摘要
Abstract 5‐Hydroxymethylfurfural (HMF) can be oxidized to 2,5‐furandicarboxylic acid (FDCA) for the production of biorenewable plastics to replace fossil resourced polyethylene terephthalate (PET). Development of a highly efficient electrocatalyst using renewable electricity as energy input is highly desired. In this work, Ru cluster‐embedded Ni(OH) 2 nanosheets [Ru/Ni(OH) 2 ] were synthesized and exploited as electrochemical catalysts for the conversion of HMF to FDCA. Ru/Ni(OH) 2 exhibited significantly improved current density (40 mA cm −2 at 1.41 V vs. reversible hydrogen electrode) of over 7.7 times in comparison with Ni(OH) 2 , and nearly 100 % conversion degree for HMF and 98.5 % selectivity towards FDCA were obtained. Operando Raman experiments revealed the catalysis was facilitated by the interconversion between Ni 3+ and Ni 2+ . Density functional theory calculations further revealed the effect of Ru clusters of Ni(OH) 2 , thereby promoting HMF adsorption capacity on Ni sites to boost HMF oxidation activity. This work provides a novel strategy using Ru clusters to modify earth abundant Ni based catalyst for HMF oxidation to obtain high‐value biomass‐derived products.
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